烟气脱硝尿素单元制与公用制水解工艺技术比较

姜艳靓,朱林,李枭鸣,王娴娜

电力建设 ›› 2015, Vol. 36 ›› Issue (3) : 114-118.

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电力建设 ›› 2015, Vol. 36 ›› Issue (3) : 114-118. DOI: 10.3969/j.issn.1000-7229.2015.03.020
发电技术

烟气脱硝尿素单元制与公用制水解工艺技术比较

  • 姜艳靓1,2,朱林1,2,李枭鸣1,2,王娴娜1,2
作者信息 +

Comparison of Unit and Public Urea Hydrolysis Process Technology for Flue Gas Denitrification

  • JIANG Yanliang1,2, ZHU Lin1,2,LI Xiaoming1,2 ,WANG Xianna1,2
Author information +
文章历史 +

摘要

结合具体工程实例,采用调查、个案研究与经验总结相结合的研究方法,比较了烟气脱硝尿素单元制与公用制这2种布置方式的安全性和空间适应性。与单元制布置方式相比,公用制布置的主要优势体现在:水解反应器互为备用,系统更安全可靠;主管道以输送氨气为主,降低了管道堵塞的可能;更能适应入口氮氧化物浓度波动;空间布置更灵活紧凑;锅炉台数越多,公用制布置方式优势越明显。对于负荷率不高、氮氧化物浓度波动较大,且位于寒冷地区的电厂,建议优先考虑公用制尿素水解布置方式。

Abstract

Combined with specific project examples, the safety reliability and space adaptability of the public urea hydrolysis technology for flue gas denitrification were compared with that of the unit system urea hydrolysis technology, as well as their arrangements, through the research methods of surveys, case studies and lessons. And compared with the unit system configuration, the main advantages of the public system are embodied in the following aspects: the public system is safer and more reliable because of the mutual standby for the hydrolysis reactor; the main pipeline based on transporting ammonia, reduces the possibility of the blockage of the pipeline; which can adapt to the concentration fluctuation of inlet NOx; the space layout is more flexible and compact; more boilers, more advantages can be taken by the public system. The public layout of urea hydrolysis system is recommended priority for the condition that the loading rate is not high, the concentration of nitrogen oxides fluctuations high and the power plant locates in cold regions.

关键词

尿素水解 / 布置方式 / 烟气脱硝 / 选择性催化还原法(SCR)

Key words

urea hydrolysis / layout / flue gas denitrification / selective catalytic reduction(SCR)

引用本文

导出引用
姜艳靓,朱林,李枭鸣,王娴娜. 烟气脱硝尿素单元制与公用制水解工艺技术比较[J]. 电力建设. 2015, 36(3): 114-118 https://doi.org/10.3969/j.issn.1000-7229.2015.03.020
JIANG Yanliang, ZHU Lin,LI Xiaoming,WANG Xianna. Comparison of Unit and Public Urea Hydrolysis Process Technology for Flue Gas Denitrification[J]. Electric Power Construction. 2015, 36(3): 114-118 https://doi.org/10.3969/j.issn.1000-7229.2015.03.020

参考文献

 
[1]刘羽,刘强,盖东飞.选择性催化还原法脱硝还原剂的制备工艺[J].华电技术,2012,33
(12): 60-62.
Liu Yu, Liu Qiang, Gai Dongfei. The preparation of the SCR DeNOX reductant[J]. Huadian Technology,2012,33(12): 60-62.
[2]马忠云,陈慧雁,刘振强,等.烟气SCR法脱硝工艺流程的设计与应用[J].电力建设,2010, 29(6):53-56.
Ma Zhongyun, Chen Huiyan, Liu Zhenqiang, et al. Process design and application of flue gas denitrification using SCR method[
J]. Electric Power Construction,2010,29(6): 53-56.
[3]Shimizu K, Satsuma A. Hydrogen assisted urea-SCR and NH3-SCR with silver–alumina as highly active and SO2 tolerant DE-
NOx catalysis[J].Applied Catalysis B-Environmental,2007, 77(1):202-205.
[4]夏怀祥,短传和.选择性催化还原法(SCR)烟气脱硝[M].北京:中国电力出版社, 2012:169-220.
[5]彭代军.锅炉烟气脱硝尿素热解与水解制氨技术对比[J].能源与节能,2014(1):188-189.
Peng Daijun. Contrast of urea pyrolysis and hydrolysis ammonia production technologies in boiler flue gas denitration
[J].Energy and Energy Conservation, 2014 (1):188-189.
[6]中电联.尿素水解工艺简介及尿素还原剂在运行中面临的问题[J/OL]. http://www.cec.org.cn/huanbao/
jienenghbfenhui/huanbaochanyejijishufuwu/chanyedongtai/tuoxiao/2012-08-01/88300.html.2012-08-01.
[7]张翔,许红胜,赵龙生.燃煤电厂脱硝还原剂的模糊综合性评判[J].电力建设,2014,35(1): 93-97.
Zhang Xiang, Xu Hongsheng, Zhao Longsheng. Fuzzy comprehensive evaluation for red-ucing agents for flue gas denitration
systems in coal-fired power plants[J]. Electric Power Construction,2014,35(1):93-97.
[8]陆雅静,熊源泉,高鸣,等.尿素/三乙醇胺湿法烟气脱硫脱硝的试验研究[J].中国电机工程学报,2008,28(5): 44-50.
Lu Yajing, Xiong Yuanquan, Gao Ming, et a1. Experimental investigation on the removal of SO2 and NOx from flue gas by aqueous
solutions of urea/triethanolamine[J].Proceedings of the CSEE, 2008, 28(5): 44-50.
[9]姚宣,沈滨,郑鹏,等.烟气脱硝用尿素水解装置性能分析[J].中国电机工程学报,2013,33(14): 38-43.
Yao Xuan, Shen Bin, Zheng Peng, et al. Characteristics of urea hydrolysis equipment for flue gas denitrification
[J].Proceedings of the CSEE,2013,33(14):38-43.
[10]惠润堂,韦飞,闫世平,等.国产首套尿素水解装置在大型火电厂的工业应用及技术优化[J].中国电力,2014(7):150-155.
Hui Runtang, Wei Fei, Yan shiping, et al. The industrial application and technical optimization of first domestically-made
urea hydrolysis unit in large power plants[J]. Electric Power,2014 (7):150-155.
[11]杜成章,刘诚.尿素热解和水解技术在锅炉烟气脱硝工程中的应用[J].华北电力技术,2010, 3(6): 39-41.
Du Chengzhang, Liu Cheng. The applications of urea pyrolysis and hydrolysis technology in  boiler flue gas denitration [J].
North China Electric Power,2010,3(6):39-41.
[12]Zheng P, Yao X, Zheng W. Design guidelines for urea hydrolysers for ammonia demand of the SCR DeNOX project in coal-
fired power plants[J]. Frontiers in Energy, 2013, 7(1):127-132.
[13]郑伟,甄志,黄波,等.烟气脱硝还原剂制备工艺[J].热力发电,2013,42(2):103-105.
Zheng Wei, Zhen Zhi, Huang Bo, et al. Preparation process of reductant for flue gas denitrification[J]. Thermal Power
Generation, 2013,42(2):103-105.
[14]汪家铭.尿素法SCR烟气脱硝技术及其应用前景[J].氮肥技术,2013,34(2):42-46.
Wang Jiaming. Urea SCR flue gas denitrification technology and its application prospect[J]. Nitrogen Fertilizer Technology,
2013,34(2):42-46.
[15]DL/T 5480—2013 火力发电厂烟气脱硝设计技术规程[S].北京:中国电力出版社,2013.
[16]柏源,李忠华,薛建明,等.尿素为还原剂燃煤烟气脱硝技术的研究与应用[J].电力科技与环保,2011,27(1):19-22.
Bai Yuan, Li Zhonghua, Xue Jianming, et al. Study and application of coal-fired flue gas denitrification with urea serving as
reducing agent[J]. Electric Power Environmental Protection,2011,27(1):19-22.
[17]Q/DG 1-J004—2010火力发电厂脱硝系统设计技术导则[S].北京:中国电力工程顾问集团公司,2010.

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