Optimization and Scheduling of Comprehensive Energy Systems Considering AmmoniaRefrigeration and Ammonia Blending in Thermal Power Plants

CHU Zhuang, YUAN Jixin

Electric Power Construction ›› 2025, Vol. 46 ›› Issue (8) : 92-104.

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Electric Power Construction ›› 2025, Vol. 46 ›› Issue (8) : 92-104. DOI: 10.12204/j.issn.1000-7229.2025.08.009
Dispatch & Operation

Optimization and Scheduling of Comprehensive Energy Systems Considering AmmoniaRefrigeration and Ammonia Blending in Thermal Power Plants

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Abstract

[Objective] In the context of dual carbon,this study aims to construct a joint model of ammonia refrigeration and thermal power units to optimize operating equipment,reduce system costs and carbon emissions,and achieve comprehensive utilization of ammonia throughout the entire process of synthetic ammonia reaction. [Methods] First,the reactants for electric to ammonia conversion were obtained through the electrolysis of water and pressure swing adsorption of air. The entire electric to ammonia conversion system was powered by renewable energy wind power,exploring ways to achieve economic and low-carbon operation in high volatility wind power scenarios. Second,the endothermic process of converting liquid ammonia into pure ammonia was linked to ammonia refrigeration,utilizing the cooling energy in a cascade manner. The reactant pure ammonia was then transported to the thermal power unit to form an ammonia blending thermal power unit,exploring the benefits of ammonia blending in thermal power units. Subsequently,the scheduling strategies of the system under different wind power penetration rates were compared and analyzed,and a market policy based on stepped carbon trading and a low-carbon economic scheduling strategy combined with carbon capture and storage market technology was proposed. A stepped carbon trading model was established to reasonably constrain the carbon emissions of the system. Finally,an optimization strategy was proposed with the objective function of minimizing the sum of gas purchase,carbon trading,wind power curtailment,coal consumption,start stop,and electricity to ammonia operation costs. [Results] By setting multiple scenarios for comparison,the results showed that the proposed strategy could reasonably allocate the output of each unit,absorb the waste air volume,and improve the economic efficiency of the integrated energy system operation. [Conclusions] The electric to ammonia conversion system considers both economic and environmental benefits when considering ammonia refrigeration,whereas the combination of ammonia gas as a refrigerant and fuel with thermal power units can help traditional thermal power plants overcome the carbon locking dilemma.

Key words

ammonia refrigeration / power to ammonia / ammonia-mixed coal power generation / integrated energy system / low carbon economic dispatch

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CHU Zhuang , YUAN Jixin. Optimization and Scheduling of Comprehensive Energy Systems Considering AmmoniaRefrigeration and Ammonia Blending in Thermal Power Plants[J]. Electric Power Construction. 2025, 46(8): 92-104 https://doi.org/10.12204/j.issn.1000-7229.2025.08.009

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氨不仅是一种成本低廉的化工原料,而且由于具有较高的能量密度、易于储运、燃烧不产生CO<sub>2</sub>等优点被认为是一种有广泛应用前景的清洁燃料。氨燃料具有替代汽油、柴油等化石燃料的应用潜力,为解决环境污染和化石能源短缺等问题提供了新的途径。本文概述了氨燃料的理化特性、燃烧特性以及与多种材料的相容性,介绍了氨作为调合燃料的性能及应用研究进展,尤其对氨-汽油燃料、氨-柴油燃料、氨-正庚烷燃料等燃料体系的研究成果进行了总结。文章集中分析了氨作为发动机燃料的机遇和挑战,尤其指出了氨燃料的生产高能耗、毒性及腐蚀性、氨的燃烧缺陷等问题,并探讨了对应的解决方案。在碳达峰、碳中和的大背景下,氨燃料在我国的发展具有后发优势。
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Ammonia is not only a low-cost chemical material, but also has some advantages such as high energy density, convenient for transportation, and combustion without CO2 emissions. Therefore, ammonia fuel is a novel clean energy with broad application prospects. Ammonia fuel has the potential to replace fossil fuels such as gasoline and diesel. Therefore, it can be anticipated that ammonia fuel would be a new way to solve environmental pollution and fossil energy shortages. This paper summarized physical and chemical properties and combustion characteristics of ammonia fuel, and compatibility of ammonia fuel and some materials was introduced as well. What’s more, the application research progress of ammonia-gasoline fuel, ammonia-diesel fuel and ammonia-heptane fuel was also summarized respectively. Furthermore, the opportunities and challenges of ammonia as a potential fuel were discussed. In particular, the problems of ammonia were pointed out, such as high energy consumption, toxicity and corrosivity, and combustion defects. Accordingly, the corresponding solutions were analyzed emphatically. Under the background of peak carbon dioxide emission and carbon neutrality, ammonia fuel had a late developing advantage in China.

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With the proposal of a "carbon reduction" global goal, hydrogen is considered the ideal clean energy, but problems such as high production cost, storage, and transportation difficulties limit the large-scale energy application of hydrogen. Used as the carrier of hydrogen. green ammonia, with the meaning of zero carbon footprint, has attracted more and more attention. This study provides an overview of the potential energy applications for green ammonia, the development of green ammonia, and the application progress of ammonia fuel. Furthermore, this study introduces the source of green ammonia. The prospect and challenges of large-scale application of green ammonia are analyzed according to the production cost, technology maturity, and policy factors of green ammonia. Presently, ship transportation and power generation are essential target application fields of ammonia fuel. However, there are still some problems, including the safety of ammonia, mixed combustion theory, and combustion system transformation, among others. An ammonia fuel cell is an essential technology for the energy conversion of ammonia. The research progress of ammonia fuel cell is introduced in detail, including oxygen ion-conducting electrolyte ammonia solid oxide fuel cell, proton-conducting electrolyte ammonia solid oxide fuel cell, proton membrane-ammonia fuel cell and alkaline ammonia fuel cell. The comprehensive analysis shows that the global carbon reduction policy is essential for developing green ammonia at this stage. In the short term, proton membrane-ammonia fuel cell and alkaline ammonia fuel cell would not be able to handle the large-scale application of ammonia fuel. Solid oxide fuel cell with high fuel flexibility is the most promising type of ammonia fuel cell.

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Abstract
碳达峰、碳中和对可再生能源提出了更迫切的发展要求。为缓解电网调峰压力的同时降低碳排放,提出了一种基于绿证碳交易机制的风火蓄联合调峰控制策略。该策略为分层控制,上层模型为保证抽蓄电站的削峰填谷效果和收益,以净负荷峰谷差最小和抽蓄收益最大为目标;下层模型以系统总运行成本最低为目标,并引入了划分区间的阶梯式碳交易机制和量化罚款幅度的绿色证书交易机制,旨在保证系统经济性的同时满足低碳性。仿真结果表明,所提出的绿证碳交易机制控制策略可减少火电机组出力1.69%,降低系统总运行成本4.09%,验证了策略在低碳经济发展方面的作用。
LI Junhui, LUO Xuanzhong, ZHU Xingxu, et al. Peak regulation control strategy of wind-thermal-storage combined based on green certificate-carbon trading mechanism[J]. Electric Power Construction, 2023, 44(7): 11-20.
Peak carbon dioxide emissions and carbon neutrality require urgent renewable energy development. This paper proposes a peak regulation control strategy for wind-thermal-storage combined with the green certificate-carbon trading mechanism to ease peak shaving pressure and reduce carbon emissions. The strategy employs a hierarchical control approach. First, the upper model aims to optimize the peak-valley difference of the net load and maximize the revenue from pumping and storage power stations, ensuring their peak-shaving, valley-filling effect, and revenue. Second, the lower model aims at the lowest total operating cost of the system and incorporates a carbon trading mechanism with segmented boundaries and a green certificate mechanism with quantified fines to ensure the economy of the system while meeting the low carbon requirements. Through simulation analysis, the proposed green certificate-carbon trading mechanism control strategy can reduce the output of thermal power units by 1.69% and the total operating cost of the system by 4.09%, verifying the role of the strategy in developing a low-carbon economy.
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Abstract
为了进一步降低综合能源系统(integrated energy system,IES)碳排放量,提升其能源利用率,提出了一种在阶梯式碳交易机制下考虑需求响应(demand response,DR)的IES优化调度策略。首先从需求响应角度出发,考虑到多种能源之间具备协同互补与灵活转换的能力,引入电-气-热的横向时移与纵向互补替代策略并构建DR模型;其次从全生命周期评估的角度出发,阐述碳排放权初始配额模型,并对其加以修正,然后引入阶梯式碳交易机制,对IES的碳排放进行约束;最后以能源购买成本、碳排放交易成本、设备维护成本、需求响应成本之和最小化为目标,并考虑安全约束构建低碳优化调度模型。利用Matlab软件将原问题转化为混合整数线性问题,并使用CPLEX求解器对模型进行优化求解。算例结果表明,在阶梯式碳交易机制下考虑碳交易成本和需求响应,可以使IES的运行总成本下降5.69%,碳排放量降低17.06%,显著提高了IES的可靠性、经济性和低碳性。
WANG Limeng, LIU Xuemeng, LI Yang, et al. Low-carbon optimal dispatch of integrated energy system considering demand response under the tiered carbon trading mechanism[J]. Electric Power Construction, 2024, 45(2): 102-114.

To further reduce the carbon emissions of integrated energy systems (IES) and improve their energy utilization, an IES optimization scheduling strategy considering demand response (DR) under a stepped carbon trading mechanism was proposed. First, from the perspective of demand response (DR), considering the synergistic complementarity and flexible conversion ability of multiple energy sources, lateral time-shifting and vertical complementary alternative strategies for electricity, gas, and heat were introduced, and a DR model was constructed. Second, from the perspective of life-cycle assessment, the initial quota model of carbon emissions allowances was elaborated and revised. Subsequently, we introduced a tiered carbon trading mechanism that imposes a certain degree of constraint on the carbon emissions of IES. Finally, the sum of the energy purchase, carbon emission transaction, equipment maintenance, and demand response costs was minimized, and a low-carbon optimal scheduling model was constructed considering the safety constraints. This model transforms the original problem into a mixed-integer linear problem using Matlab software and optimizes the model using the CPLEX solver. The example results show that considering the carbon trading cost and demand response under the tiered carbon trading mechanism, the total operating cost of the IES is reduced by 5.69%, and the carbon emissions are reduced by 17.06%, which significantly improves the reliability, economy, and low-carbon performance of the IES.

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National Natural Science Foundation of China(52077030)
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